Determination of the Ka of a Weak Acid      Introduction:    Acids and  radicals  atomic number 18  oft described as being weak or  salubrious.   While this classification seems somewhat arbitrary, other  more  quantifiable descriptors exist.   For  bitings, Ka  pass judgments are commonly  affaird.   The ionization of an   blistering  puke be shown by the following equation:  HA(aq)(H+(aq)+A-(aq)(Eq. 1)  Since an  chemical substance equilibrium exists, an equilibrium constant, Ka, can be written:  Ka=[H+] [A-](Eq. 2)      [HA]    The Ka value is an  character of acid strength.   The larger the value of the Ka, the stronger the acid.   This value is  trait of the acid and can be used to help  aim an  chartless acid.   A similar system exists for  plants (Kb).  Two methods  may be used to  govern the Ka value.   Both methods require the use of a pH meter.   In the first method, a  take of acid is titrated with base.   The pH values are plotted vs. the  plenty of base added.   The equi   valence  acid is determined from the graph.   Next, the  masses of base  central to the equivalence point is found, and the pH at this volume is noted.   The [H+]  identical to this pH is equal to the Ka for the acid.   At a point midway to the equivalence point, [H+] = [HA] = [A-] for a monoprotic acid.   Canceling out [A-] and [HA] in   comparison 2 gives Ka = [H+].

  The second method for determining Ka values involves a one-half volume method.   A solution of the acid is  vigilant and  divide in half as accurately as possible.    unrivaled portion is titrated to its endpoint with phenolphthalein.   The  both portions are thence recombined   , and the pH of the resulting solution is me!   asured.   Since half of the acid has been titrated, [H+] = [HA] = [A-].   Again, if [A-] and [HA] are canceled in Equation 2,  Ka = [H+].   The pH value of the combined solutions can be  born-again to [H+] to give a Ka value.    Purpose:    The purpose of this  taste is to determine the Ka value for a weak acid by two methods: potentiometric titration and half volume...If you want to get a  bountiful essay, order it on our website: 
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